Adeyemo, Aderonke Ajibola ; Mukherjee, Partha Sarathi (2018) Coordination-driven self-assembly of discrete Ru6–Pt6 prismatic cages Beilstein Journal of Organic Chemistry, 14 . pp. 2242-2249. ISSN 1860-5397
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Official URL: http://doi.org/10.3762/bjoc.14.199
Related URL: http://dx.doi.org/10.3762/bjoc.14.199
Abstract
The coordination-driven self-assembly of two new Ru6-Pt6 hexanuclear trigonal prismatic cages comprising arene-ruthenium(II) clips (1a(NO3)2 and 1b(NO3)2 ) and a tritopic platinum(II) metalloligand 2 has been performed in methanol at room temperature. The [3 + 2] hexanuclear cages 3a and 3b were isolated in good yields and characterized by well-known spectroscopic techniques including multinuclear NMR, mass spectrometry, UV-vis and infrared studies. Geometry optimization revealed the shapes and sizes of these hexanuclear prismatic cages. The combination of ruthenium and platinum metal center in a one-pot self-assembly reaction showcases the construction of aesthetically elegant heterometallic structures in supramolecular chemistry leading to the formation of a single major product.
Item Type: | Article |
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Source: | Copyright of this article belongs to BioMed Central Ltd. |
ID Code: | 118619 |
Deposited On: | 26 May 2021 07:24 |
Last Modified: | 26 May 2021 07:24 |
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