Gopinathan, Sarada ; Unni, I. R. ; Gopinathan, C. ; Puranik, Vedavati G. ; Tavale, S. S. ; Guru Row, T. N. (1987) Synthesis and crystal structure of carbonylchlorobis(triphenylphosphine)dithio-formatoruthenium(II)tetrahydrofuran [C42H39ClO2P2S2Ru] Polyhedron, 6 (10). pp. 1859-1861. ISSN 0277-5387
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S02775...
Related URL: http://dx.doi.org/10.1016/S0277-5387(00)81095-5
Abstract
The title complex [RuCl(CO)(PPh3)2(S2CH)](thf) has been prepared by the insertion of carbon disulphide into the Ru---H bond of [RuHClCO(PPh3)2(4-Vp)] followed by crystallization from a mixture of benzene and thf (4-Vp = 4-vinyl pyridine). Its structure has been determined by single crystal X-ray diffraction methods. The crystals are triclinic, space group P1-, z = 2, a = 10.042(1), b = 11.216(1), c = 17.772(2) Å, α = 99.80(1), β = 93.26(1) and γ = 90.86(1)°. The structure, which has been refined to R = 0.078 for 4949 reflections, is a distorted octahedron.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 11854 |
| Deposited On: | 13 Nov 2010 13:47 |
| Last Modified: | 03 Jun 2011 04:44 |
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