Assembling Zirconium and Calcium Moieties through an Oxygen Center for an Intramolecular Hydroamination Reaction: A Single System for Double Activation

Mukherjee, Arup ; Nembenna, Sharanappa ; Sen, Tamal K. ; Sarish, Sankaranarayana Pillai ; Ghorai, Pradip Kr. ; Ott, Holger ; Stalke, Dietmar ; Mandal, Swadhin K. ; Roesky, Herbert W. (2011) Assembling Zirconium and Calcium Moieties through an Oxygen Center for an Intramolecular Hydroamination Reaction: A Single System for Double Activation Angewandte Chemie International Edition, 50 (17). pp. 3968-3972. ISSN 1433-7851

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Official URL: http://doi.org/10.1002/anie.201100022

Related URL: http://dx.doi.org/10.1002/anie.201100022

Abstract

One for two: A zirconium compound combined with a main-group alkaline earth metal through an oxygen bridge has been synthesized. A number of primary and secondary aminoalkenes were successfully converted into cyclic products using this heterobimetallic complex as catalyst. The calcium center activates primary aminoalkenes, and the zirconium center activates secondary aminoalkenes.

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ID Code:118377
Deposited On:20 May 2021 15:53
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