MUKHERJEE, ARUP ; SEN, TAMAL K ; MANDAL, SWADHIN K ; KRATZERT, DANIEL ; STALKE, DIETMAR ; DÖRING, ALEXANDER ; SCHULZKE, CAROLA (2011) Phenalenyl-based ligand for transition metal chemistry: Application in Henry reaction Journal of Chemical Sciences, 123 (2). pp. 139-144. ISSN 0974-3626
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Official URL: http://doi.org/10.1007/s12039-011-0107-2
Related URL: http://dx.doi.org/10.1007/s12039-011-0107-2
Abstract
We report the synthesis and characterization of the first transition metal complex of a phenalenyl-based ligand. The reaction of Cu(OAc)2.H2O with 9-N-methylamino-1-N ′-methylimino-phenalene (LH) in 1:1 stoichiometric ratio results in the formation of a mononuclear copper complex [LCu(OAc)] (1). The molecular structure of 1 was established by X-ray crystallography. The electrochemistry of 1 indicates the formation of an anionic radical by one electron reduction into the non-bonding molecular orbital of the phenalenyl system. The complex 1 efficiently catalyses the C–C bond forming Henry reaction
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer Nature Switzerland AG. |
| ID Code: | 118375 |
| Deposited On: | 20 May 2021 15:43 |
| Last Modified: | 20 May 2021 15:43 |
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