Patra, Ayan ; Sen, Tamal K. ; Bhattacharyya, Rangeet ; Mandal, Swadhin K. ; Bera, Manindranath (2012) Diversity of carboxylate binding in a new tetranuclear zinc cluster: correlation between spectroscopic investigations and carboxylate binding modes RSC Advances, 2 (5). p. 1774. ISSN 2046-2069
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Official URL: http://doi.org/10.1039/C2RA01317G
Related URL: http://dx.doi.org/10.1039/C2RA01317G
Abstract
A new tetranuclear ZnII4 cluster has been prepared and characterized by exploiting the flexibility, chelating ability and bridging potential of a carboxylate rich μ-bis(tetradentate) ligand. The acetate and benzoate functionalities of the ligand display both monodentate terminal and syn–anti bidentate bridging binding modes in the cluster. The binding modes of carboxylate have been investigated by a combined approach of X-ray crystallography, FTIR, solution and solid state 13C NMR spectroscopic techniques.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 118364 |
| Deposited On: | 20 May 2021 13:55 |
| Last Modified: | 20 May 2021 13:55 |
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