Daw, Prosenjit ; Petakamsetty, Ramu ; Sarbajna, Abir ; Laha, Siladitya ; Ramapanicker, Ramesh ; Bera, Jitendra K. (2014) A Highly Efficient Catalyst for Selective Oxidative Scission of Olefins to Aldehydes: Abnormal-NHC–Ru(II) Complex in Oxidation Chemistry Journal of the American Chemical Society, 136 (40). pp. 13987-13990. ISSN 0002-7863
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Official URL: http://doi.org/10.1021/ja5075294
Related URL: http://dx.doi.org/10.1021/ja5075294
Abstract
The utility and selectivity of the catalyst [Ru(COD)(L1)Br2] (1) bearing a fused π-conjugated imidazo[1,2-a][1,8]naphthyridine-based abnormal N-heterocyclic carbene ligand L1 is demonstrated toward selective oxidation of C═C bonds to aldehydes and C≡C bonds to α-diketones in an EtOAc/CH3CN/H2O solvent mixture at room temperature using a wide range of substrates, including highly functionalized sugar- and amino acid-derived compounds.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 118296 |
| Deposited On: | 19 May 2021 20:09 |
| Last Modified: | 19 May 2021 20:09 |
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