Sau, Samaresh Chandra ; Bhattacharjee, Rameswar ; Vardhanapu, Pavan K. ; Vijaykumar, Gonela ; Datta, Ayan ; Mandal, Swadhin K. (2016) Metal-Free Reduction of CO2to Methoxyborane under Ambient Conditions through Borondiformate Formation Angewandte Chemie International Edition, 55 (48). pp. 15147-15151. ISSN 1433-7851
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Official URL: http://doi.org/10.1002/anie.201609040
Related URL: http://dx.doi.org/10.1002/anie.201609040
Abstract
An abnormal N-heterocyclic carbene (aNHC) based homogeneous catalyst has been used for the reduction of carbon dioxide to methoxyborane in the presence of a range of hydroboranes under ambient conditions and resulted in the highest turnover number of 6000. A catalytically active reaction intermediate, [aNHC-H⋅9BBN(OCOH)2] was structurally characterized and authenticated by NMR spectroscopy. A detailed mechanistic cycle of this catalytic process via borondiformate formation has been proposed from tandem experimental and computational experiments.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| ID Code: | 118294 |
| Deposited On: | 19 May 2021 19:59 |
| Last Modified: | 19 May 2021 19:59 |
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