Abnormal NHC supported palladacycles: Regioselective arylation of heteroarenes via decarboxylation

Jose, Anex ; Vijaykumar, Gonela ; Vardhanapu, Pavan K. ; Mandal, Swadhin K. (2018) Abnormal NHC supported palladacycles: Regioselective arylation of heteroarenes via decarboxylation Journal of Organometallic Chemistry, 865 . pp. 51-57. ISSN 0022-328X

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Official URL: http://doi.org/10.1016/j.jorganchem.2018.01.046

Related URL: http://dx.doi.org/10.1016/j.jorganchem.2018.01.046

Abstract

We report synthesis of two new palladium(II) complexes of abnormal N-heterocyclic carbene ligands. The catalytic activity of these palladium(II) complexes was examined for the decarboxylative arylation of N-methylindole-carboxylic acids. An exclusive regioselectivity and very good yields were obtained with a variety of aryl halide partners.

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