Rajendran, N. M. ; Gautam, Nimisha ; Sarkar, Pallavi ; Ahmed, Jasimuddin ; Das, Arpan ; Das, Shubhajit ; Pati, Swapan K. ; Mandal, Swadhin K. (2021) Bicyclic (alkyl)(amino)carbene stabilized zinc(0) complex with singlet biradicaloid ground state Chemical Communications . ISSN 1359-7345
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Official URL: http://doi.org/10.1039/D1CC01298C
Related URL: http://dx.doi.org/10.1039/D1CC01298C
Abstract
A storable bicyclic (alkyl)(amino)carbene (BICAAC) stabilized two coordinate zinc(0) complex [(BICAAC)2Zn] (2) was synthesized. DFT calculations reveal that BICAAC plays a decisive role in imparting the stability to 2. This complex activates the C(sp3)–Cl bond of trityl chloride generating the Gomberg's free radical with greater efficiency than metallic Zn powder.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 118157 |
| Deposited On: | 18 May 2021 07:25 |
| Last Modified: | 18 May 2021 07:30 |
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