A diversity oriented synthesis of highly functionalized unsymmetrical biaryls through carbanion induced ring transformation of 2H-pyran-2-ones

Agarwal, Nidhi ; Saxena, Abhishek S ; Farhanullah, . ; Goel, Atul ; Ram, Vishnu J (2002) A diversity oriented synthesis of highly functionalized unsymmetrical biaryls through carbanion induced ring transformation of 2H-pyran-2-ones Tetrahedron, 58 (43). pp. 8793-8798. ISSN 0040-4020

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Official URL: http://doi.org/10.1016/S0040-4020(02)01066-9

Related URL: http://dx.doi.org/10.1016/S0040-4020(02)01066-9

Abstract

A new route for the synthesis of unsymmetrical biaryls endowed with electron withdrawing and donating substituents is delineated through base catalyzed ring transformation of 2H-pyran-2-ones with malononitrile in a single step. This procedure offers the flexibility of introducing desired functionalities in aromatic rings, which are difficult to obtain by other classical routes.

Item Type:Article
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ID Code:117897
Deposited On:06 May 2021 05:59
Last Modified:06 May 2021 05:59

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