An Expeditious Synthesis of 9,10-Dihydrophenanthrene by Condensation of 2H-Pyran-2-ones with α-Tetralone†‡

J. Ram, Vishnu ; Goel, Atul (1997) An Expeditious Synthesis of 9,10-Dihydrophenanthrene by Condensation of 2H-Pyran-2-ones with α-Tetralone†‡ Journal of Chemical Research (12). p. 460. ISSN 0308-2342

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Official URL: http://doi.org/10.1039/A704233G

Related URL: http://dx.doi.org/10.1039/A704233G

Abstract

7-Substituted 1-aryl-3-hydroxy-4-methoxycarbonyl-9,10-dihydrophenanthrene (3) and its derivatives were synthesized from 6-aryl-3-methoxycarbonyl-4-methylsulfanyl-2H-pyran-2-ones (1) by carbanion induced ring transformation reactions; the salient feature of this procedure is to provide a one-pot synthesis of functionalized polycyclic aromatic hydrocarbons.

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