Photodimerization Processes in Self-Assembled Chiral Oligo(p-phenylenevinylene) Bolaamphiphiles

George, Subi J. ; de Greef, Tom F. A. ; Bovee, Ralf ; van Dongen, Joost L. J. ; Schenning, Albertus P. H. J. ; Meijer, E. W. (2009) Photodimerization Processes in Self-Assembled Chiral Oligo(p-phenylenevinylene) Bolaamphiphiles Chemistry - An Asian Journal, 4 (6). pp. 910-917. ISSN 1861-4728

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Official URL: http://doi.org/10.1002/asia.200900031

Related URL: http://dx.doi.org/10.1002/asia.200900031

Abstract

Highly discriminating cycloaddition: An unexpected [2+2] cycloaddition in self‐assembled cation OPV‐monolayered vesicles is described. Remarkably, the photochemical reaction is chemo‐, regio‐, and stereoselective, which is most likely the result of the well‐controlled supramolecular organization of the OPV units in the monolayer.

Item Type:Article
Source:Copyright of this article belongs to John Wiley & Sons, Inc.
Keywords:Amphiphiles; Conjugation; Dimerization; Photochemistry; Self‐Assembly.
ID Code:117787
Deposited On:03 May 2021 10:38
Last Modified:03 May 2021 10:38

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