Extended phenylene based microporous organic polymers with selective carbon dioxide adsorption

Abstract

Two microporous conjugated polymers with extended phenylene backbones have been synthesized through Suzuki cross-coupling reactions. The structure and the pores of the polymers have been controlled by the use of para- and meta-structure directing 1,3,5-triphenyl tribromide monomers. Gas sorption studies revealed an unprecedented CO₂ selectivity over N₂ for these conjugated polymer networks. The networks have furthermore been tested as hydrogen storage materials and showed significant hydrogen uptake at high pressures.