Dhiman, Shikha ; Jain, Ankit ; Kumar, Mohit ; George, Subi J. (2017) Adenosine-Phosphate-Fueled, Temporally Programmed Supramolecular Polymers with Multiple Transient States Journal of the American Chemical Society, 139 (46). pp. 16568-16575. ISSN 0002-7863
Full text not available from this repository.
Official URL: http://doi.org/10.1021/jacs.7b07469
Related URL: http://dx.doi.org/10.1021/jacs.7b07469
Abstract
Natural systems have been an inspiration to synthetic supramolecular chemistry. Synthetic demonstrations of dissipative biological systems such as actin filaments are a formidable scientific challenge in attaining future life-like materials. Dynamic instability of such structures beckons control of self-organization in the temporal regimes. In this study, we present a fuel-dependent helical assembly of a supramolecular polymer. We further attempt the synthetic manifestation of a temporally programmable self-assembly. Additionally, the fuel-induced chiral (re)organization with the employment of various enzymes singularly and in tandem have resulted in designing a multistate transient self-assembly. These parameter modulations result in controllable lifetimes and rates. We thus report, for the first time, a temporally programmed multistate reorganization of self-assembly.
Item Type: | Article |
---|---|
Source: | Copyright of this article belongs to American Chemical Society. |
ID Code: | 117714 |
Deposited On: | 30 Apr 2021 08:45 |
Last Modified: | 30 Apr 2021 08:45 |
Repository Staff Only: item control page