Bioinspired, ATP-driven co-operative supramolecular polymerization and its pathway dependence

Mishra, Ananya ; Korlepara, Divya B. ; Balasubramanian, Sundaram ; George, Subi J. (2020) Bioinspired, ATP-driven co-operative supramolecular polymerization and its pathway dependence Chemical Communications, 56 (10). pp. 1505-1508. ISSN 1359-7345

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Official URL: http://doi.org/10.1039/C9CC08790G

Related URL: http://dx.doi.org/10.1039/C9CC08790G

Abstract

A bio-inspired, ATP-driven nucleation growth assembly is demonstrated using an amphiphilic naphthalene diimide (NDI) derivative appended with guanidinium receptors to promote specific salt-bridge type interaction with nucleotide phosphates. Detailed spectroscopic and microscopic probing revealed a pathway-dependent co-operative self-assembly to yield two-dimensional and scrolled nano-tubular bilayer assemblies under kinetic and thermodynamic conditions, respectively.

Item Type:Article
Source:Copyright of this article belongs to The Royal Society of Chemistry.
ID Code:117691
Deposited On:29 Apr 2021 12:53
Last Modified:29 Apr 2021 12:53

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