Spin Transition in a Chainlike Supramolecular Iron(II) Complex

Rajadurai, Chandrasekar ; Schramm, Frank ; Brink, Susan ; Fuhr, Olaf ; Ghafari, Mohamed ; Kruk, Robert ; Ruben, Mario (2006) Spin Transition in a Chainlike Supramolecular Iron(II) Complex Inorganic Chemistry, 45 (25). pp. 10019-10021. ISSN 0020-1669

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Official URL: http://doi.org/10.1021/ic0612350

Related URL: http://dx.doi.org/10.1021/ic0612350

Abstract

A one-dimensional supramolecular head-to-tail N+ -H...N-type hydrogen-bonded chain of the complex [FeII(L)2H](ClO4)3.MeOH [L = 4'-(4'''-pyridyl)-1,2':6'1''-bis(pyrazolyl)pyridine] exhibits a reversible, thermally driven spin transition at 286 K with a hysteresis loop of ca. 2 K.

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ID Code:117517
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