“Super hybrid tridentate ligands”: 4-substituted-2-(1-butyl-1H-1,2,3-triazol-4-yl)-6-(1H-pyrazol-1-yl)pyridine ligands coordinated to Fe(ii) ions display above room temperature spin transitions

Chandrasekhar, Naisa ; Chandrasekar, Rajadurai (2010) “Super hybrid tridentate ligands”: 4-substituted-2-(1-butyl-1H-1,2,3-triazol-4-yl)-6-(1H-pyrazol-1-yl)pyridine ligands coordinated to Fe(ii) ions display above room temperature spin transitions Dalton Transactions, 39 (41). p. 9872. ISSN 1477-9226

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Official URL: http://doi.org/10.1039/C0DT00373E

Related URL: http://dx.doi.org/10.1039/C0DT00373E

Abstract

A series of novel “super hybrid tridentate ligands” based on (2-(1-butyl-1H-1,2,3-triazol-4-yl)-6-(1H-pyrazol-1-yl)pyridine (tpp) derivatives were synthesized. Their Fe(II) complexes display around (T½ = 287 K) and above room temperature (T½ ≫ 375 K) spin transition temperatures.

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