Basak, Supratim ; Hui, Pramiti ; Boodida, Sathyanarayana ; Chandrasekar, Rajadurai (2012) Micropatterning of Metallopolymers: Syntheses of Back-to-Back Coupled Octylated 2,6-Bis(pyrazolyl)pyridine Ligands and Their Solution-Processable Coordination Polymers The Journal of Organic Chemistry, 77 (7). pp. 3620-3626. ISSN 0022-3263
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Official URL: http://doi.org/10.1021/jo300050m
Related URL: http://dx.doi.org/10.1021/jo300050m
Abstract
This paper presents a 10-step synthetic route for the preparation of a series of new back-to-back coupled 2,6-bis(pyrazol-1-yl)pyridine (bpp) ligands (L0–L3) decorated with tetraoctyl chains. Ligand L1 self-assembles with Zn2+ ion to form a highly soluble metallo-supramolecular polymer 1 with Mn ∼ 9600 g/mol. To demonstrate the processability of polymer 1, by following a “top-down” approach periodic one-dimensional fluorescent microstripes were fabricated on a silica substrate.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 117424 |
| Deposited On: | 23 Apr 2021 09:06 |
| Last Modified: | 23 Apr 2021 09:06 |
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