Tungsten Trioxide (WO3) Nanoparticles as a New Anode Material for Sodium-Ion Batteries

Santhosha, A. L ; Das, Shyamal K ; Bhattacharyya, Aninda J (2016) Tungsten Trioxide (WO3) Nanoparticles as a New Anode Material for Sodium-Ion Batteries Journal of Nanoscience and Nanotechnology, 16 (4). pp. 4131-4135. ISSN 1533-4880

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Official URL: http://doi.org/10.1166/jnn.2016.11786

Related URL: http://dx.doi.org/10.1166/jnn.2016.11786

Abstract

Tungsten trioxide (WO3) is investigated for the first time as an anode material for sodium-ion batteries. Pristine WO3 displays a discharge potential plateau at 1 V and exhibits a 1st discharge cycle sodium storage capacity of 640 mAh g-1. Electronic wiring of WO3 with graphene oxide (GO, 1% by weight) led to a significant increase in the storage capacity and cyclability of WO3. As a result, the discharge capacity of 1% GO-WO3 is enhanced to 927 mAh g-1 in the 1st discharge cycle. The electrochemical intercalation of Na in to WO3 and (1%) GO-WO3 as obtained from galvanostatic charge/discharge cycling is also supported by cyclic voltammetry.

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