Jemmis, Eluvathingal D. ; Subramanian, Govindan ; Prasad, Bharatam V. ; Tsuzuki, Seiji ; Tanabe, Kazutoshi (1993) Contrasting Structures of Pyramidal Carbocations and Their Silicon Analogues Angewandte Chemie International Edition in English, 32 (6). pp. 865-867. ISSN 0570-0833
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Official URL: http://doi.org/10.1002/anie.199308651
Related URL: http://dx.doi.org/10.1002/anie.199308651
Abstract
Caution is required when drawing analogies between carbon and silicon compounds. This is proven by the calculations presented here, according to which the Si compounds analogous to 1 do not correspond to minima on the potential energy surfaces. The most stable structures are of type 3. Reminiscent of nido‐B5H9, structures 2 with H bridges also correspond to local minima, although these are high in energy. X = BH, SiH+, Si.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| ID Code: | 116702 |
| Deposited On: | 12 Apr 2021 11:55 |
| Last Modified: | 12 Apr 2021 11:55 |
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