Bharatam, Prasad V ; Amita, . (2002) Negative hyperconjugative interactions in S-nitrosothiols: a theoretical study Tetrahedron Letters, 43 (46). pp. 8289-8291. ISSN 0040-4039
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Official URL: http://doi.org/10.1016/S0040-4039(02)02011-7
Related URL: http://dx.doi.org/10.1016/S0040-4039(02)02011-7
Abstract
The S–N interactions are very weak in S-nitrosothiols because the nO→σ*S–N negative hyperconjugative interaction weakens the σ bond, though the pπ–pπ interactions are reasonably strong.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier B.V. |
| ID Code: | 116691 |
| Deposited On: | 12 Apr 2021 11:47 |
| Last Modified: | 12 Apr 2021 11:47 |
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