Nancy, . ; Ghosh, Soma ; Singh, Nishan ; Kaur Nanda, Gurmeet ; Venugopalan, P. ; Bharatam, Prasad V. ; Trehan, Sanjay (2003) Origin of 1, 3-induction in the addition of alkyl lithium to imines bearing an N-stereogenic center Chemical Communications (12). p. 1420. ISSN 1359-7345
Full text not available from this repository.
Official URL: http://doi.org/10.1039/B300478C
Related URL: http://dx.doi.org/10.1039/B300478C
Abstract
The origin of diastereoselectivity in the addition of alkyl lithium to chiral Schiff bases has been investigated experimentally and theoretically and the formation of the major diastereomer can be explained from the energy minimized structure of the Schiff base in which the phenyl group has been found to orient in such a manner that it posed lesser steric hindrance to the incoming nucleophile as compared to the alkyl group
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 116681 |
| Deposited On: | 12 Apr 2021 11:43 |
| Last Modified: | 12 Apr 2021 11:43 |
Repository Staff Only: item control page
