Effect of iminic nitrogen substituents on [4+2] versus [3+2] cycloaddition pathways in reactions of nitrosoalkenes with simple acyclic imines: an experimental and theoretical investigation

Marwaha, Alka ; Bharatam, P.V. ; Mahajan, M.P. (2005) Effect of iminic nitrogen substituents on [4+2] versus [3+2] cycloaddition pathways in reactions of nitrosoalkenes with simple acyclic imines: an experimental and theoretical investigation Tetrahedron Letters, 46 (47). pp. 8253-8256. ISSN 0040-4039

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Official URL: http://doi.org/10.1016/j.tetlet.2005.08.142

Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.08.142

Abstract

The results of experimental and theoretical investigations on the mechanism of competitive [3+2] versus [4+2] cycloaddition reactions of simple acyclic imines with nitrosoalkenes are reported. The effect of substituents on the iminic nitrogen in influencing the cycloaddition pathways has been meticulously explored.

Item Type:Article
Source:Copyright of this article belongs to Elsevier B.V.
Keywords:Schiff’s Bases; Nitrosoalkenes; Nitrones; Oxazines; Guassian 94w.
ID Code:116646
Deposited On:12 Apr 2021 11:14
Last Modified:12 Apr 2021 11:14

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