Ionic relaxation in AgI-Ag2O-TeO2 glasses

Dutta, D. ; Ghosh, A. (2004) Ionic relaxation in AgI-Ag2O-TeO2 glasses Journal of Physics: Condensed Matter, 16 (15). pp. 2617-2624. ISSN 0953-8984

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Official URL: http://iopscience.iop.org/0953-8984/16/15/013

Related URL: http://dx.doi.org/10.1088/0953-8984/16/15/013

Abstract

We report the ionic conductivity relaxation in fast ion conducting glasses in the system xAgI-(1- x)(0.40Ag2O-0.60TeO2) in the temperature range 128-303 K and in the frequency range 10 Hz-2 MHz. We have observed that the conductivity relaxation can be described by the highly non-exponential Kohlrausch-Williams-Watts function. The Ag+ ions have to overcome the same barrier while relaxing as well as while conducting. We have further observed that the migration of Ag+ ions in the glassy matrix is highly cooperative and the cooperation is extended as the AgI content is increased.

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Deposited On:13 Nov 2010 14:06
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