Patel, Neha ; Arfeen, Minhajul ; Sood, Radhika ; Khullar, Sadhika ; Chakraborti, Asit K. ; Mandal, Sanjay K. ; Bharatam, Prasad V. (2018) Can Remote N-Heterocyclic Carbenes Coordinate with Main Group Elements? Synthesis, Structure, and Quantum Chemical Analysis of N+ -Centered Complexes Chemistry - A European Journal, 24 (24). pp. 6418-6425. ISSN 0947-6539
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Official URL: http://doi.org/10.1002/chem.201705999
Related URL: http://dx.doi.org/10.1002/chem.201705999
Abstract
Remote N‐heterocyclic carbenes (rNHCs), such as N‐methyl‐4‐pyridylidene, are known to form coordination complexes with TMs. Herein, it is established that rNHCs can also coordinate to the N+ centre. Synthesis of some novel divalent NI complexes with the general formula (rNHC)→N+←(NHC) and (rNHC)→N+←(rNHC) was achieved, and X‐ray diffraction studies supported the coordination bond character between the rNHCs and the N+ centre. Quantum chemical analysis established the presence of divalent NI character at the central nitrogen in these systems.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| Keywords: | Carbene Ligands; Divalent Ni Compounds; Donor–acceptor Systems; Quantum Chemistry; X-ray Diffraction. |
| ID Code: | 116314 |
| Deposited On: | 12 Apr 2021 09:23 |
| Last Modified: | 12 Apr 2021 09:23 |
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