Organic Chlorine as a Hydrogen-Bridge Acceptor: Evidence for the Existence of Intramolecular O-H⋅⋅⋅Cl-C Interactions in Somegem-Alkynols

Banerjee, Rahul ; Desiraju, Gautam R. ; Mondal, Raju ; Howard, Judith A. K. (2004) Organic Chlorine as a Hydrogen-Bridge Acceptor: Evidence for the Existence of Intramolecular O-H⋅⋅⋅Cl-C Interactions in Somegem-Alkynols Chemistry - A European Journal, 10 (14). pp. 3373-3383. ISSN 0947-6539

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Official URL: http://doi.org/10.1002/chem.200400003

Related URL: http://dx.doi.org/10.1002/chem.200400003

Abstract

The acceptor capabilities of “organic” halogen, CX (X=F, Cl, Br, I), with respect to hydrogen bonding are controversial, and unactivated organic chlorine is generally deemed to be a poor acceptor.

Item Type:Article
Source:Copyright of this article belongs to John Wiley & Sons, Inc..
Keywords:Chlorine; Crystal Engineering; Hydrogen Bonds; Interaction Energy; Supramolecular Chemistry.
ID Code:115937
Deposited On:17 Mar 2021 05:20
Last Modified:17 Mar 2021 05:20

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