Pachfule, Pradip ; Das, Raja ; Poddar, Pankaj ; Banerjee, Rahul (2010) Structural, Magnetic, and Gas Adsorption Study of a Two-Dimensional Tetrazole-Pyrimidine Based Metal−Organic Framework Crystal Growth & Design, 10 (6). pp. 2475-2478. ISSN 1528-7483
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Official URL: http://doi.org/10.1021/cg1003726
Related URL: http://dx.doi.org/10.1021/cg1003726
Abstract
A new two-dimensional (2D) metal−organic framework, Cu-TP-1, has been synthesized under solvothermal conditions (DMF) from the transition metal cation Cu(II) and 2-tetrazole pyrimidine (C5H5N6, H-TP). The structure has been determined by single crystal X-ray crystallography which shows a (6,3) honeycomb 2D net with perpendicular one-dimensional channels. Permanent porosity of Cu-TP-1 has been determined by the nitrogen adsorption isotherm. Cu-TP-1 show interesting H2 and CO2 uptake. CO2 uptake of Cu-TP-1 (at 298 K, 1 atm pressure) is seen to be comparable to the recently reported ZIF-95 which outperforms ZIF-100 and BPL carbon. The magnetic properties show an antiferromagnetically coupled Cu···Cu interaction down to 8 K with a Weiss temperature around 108 K.
Item Type: | Article |
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Source: | Copyright of this article belongs to American Chemical Society. |
Keywords: | Pyrimidine; Ligands; Crystal Structure; Metal Organic Frameworks; Physical and Chemical Processes. |
ID Code: | 115915 |
Deposited On: | 16 Mar 2021 12:12 |
Last Modified: | 16 Mar 2021 12:12 |
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