Pachfule, Pradip ; Banerje, Rahul (2011) Structural and gas adsorption study of a two-dimensional copper–tetrazole based metal–organic framework Current Science, 101 (7). pp. 34-38. ISSN 0011-3891
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Official URL: http://www.currentscience.ac.in/Volumes/101/07/089...
Related URL: http://dx.doi.org/https://www.jstor.org/stable/24079126
Abstract
A new two-dimensional (2D) metal–organic framework, Cu1(4-TBA)1(DMBP)1·DMF (Cu-TBA-3), has been synthesized under solvothermal condition from transition metal cation Cu(II), predesigned ligand 4-(1Htetrazole-5-yl)benzoic acid (4-TBA) and coligand 4,4′-dimethyl-2,2′-bipyridine (DMBP). The structure has been determined by single crystal X-ray crystallography which shows layered 2D structure with square shaped one-dimensional channels. Cu-TBA-3 shows 0.69 wt% H2 (at 77 K, 1 atm) and 1.65 mmol/g CO2 (at 298 K, 1 atm) uptake.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Current Science Association, Bengaluru. |
| ID Code: | 115907 |
| Deposited On: | 16 Mar 2021 10:43 |
| Last Modified: | 16 Mar 2021 10:43 |
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