Panda, Tamas ; Pachfule, Pradip ; Banerjee, Rahul (2011) Template induced structural isomerism and enhancement of porosity in manganese(ii) based metal–organic frameworks (Mn-MOFs) Chemical Communications, 47 (27). p. 7674. ISSN 1359-7345
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Official URL: http://doi.org/10.1039/C1CC12278A
Related URL: http://dx.doi.org/10.1039/C1CC12278A
Abstract
Three new metal–organic framework isomers have been synthesized by using the organic linker 5-triazole isophthalic acid and Mn(NO3)2·xH2O. Structural conversions from non-porous to porous MOFs due to the template effect have been observed. The cross-sectional pore apertures of the resulting Mn-MOFs are comparable to the molecular dimensions of the template (pyrazine and 4,4′-bipyridine). The periodic increased porosity in Mn-MOFs depending on the size of the template used has been further confirmed by the CO2 adsorption isotherms.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to The Royal Society of Chemistry. |
| ID Code: | 115906 |
| Deposited On: | 16 Mar 2021 10:31 |
| Last Modified: | 16 Mar 2021 10:31 |
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