Solution mediated phase transformation (RHO to SOD) in porous Co-imidazolate based zeolitic frameworks with high water stability

Biswal, Bishnu P. ; Panda, Tamas ; Banerjee, Rahul (2012) Solution mediated phase transformation (RHO to SOD) in porous Co-imidazolate based zeolitic frameworks with high water stability Chemical Communications, 48 (97). p. 11868. ISSN 1359-7345

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Official URL: http://doi.org/10.1039/C2CC36651G

Related URL: http://dx.doi.org/10.1039/C2CC36651G

Abstract

Here we report a highly porous, water stable Co based ZIF [CoNIm (RHO)] and its solution mediated phase transformation to a less porous and water unstable ZIF [CoNIm (SOD)]. CoNIm (RHO) has high Langmuir surface area [2087 m2 g−1] as well as high water adsorption [200 cm3 (STP) g−1] capacity.

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ID Code:115873
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