Kinetics of step polymerization with unequal reactivities

Gandhi, K. S. ; Babu, S. V. (1979) Kinetics of step polymerization with unequal reactivities AIChE Journal, 25 (2). pp. 266-272. ISSN 0001-1541

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/aic.690...

Related URL: http://dx.doi.org/10.1002/aic.690250208

Abstract

The kinetics of step polymerization involving a monomer with unequal reactivities has been obtained. The polydisperity index (PDI) has also been calculated both as a function of conversion and the initial stoichiometric ratio. It has been shown that the usually assumed maximum value of 2 for PDI can lead to erroneous molecular weight.

Item Type:Article
Source:Copyright of this article belongs to American Institute of Chemical Engineers.
ID Code:11527
Deposited On:16 Nov 2010 13:50
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