Gurjar, Mukund K. ; Borhade, Ramdas G. ; Puranik, Vedavati G. ; Ramana, C. V. (2006) Total synthesis of (−)-radicamine B Tetrahedron Letters, 47 (39). pp. 6979-6981. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2006.07.120
Abstract
The synthesis of a chiral cyclic nitrone with l-arabino configuration and its application in the total synthesis of radicamine B is reported. An agreement in the spectral data with natural radicamine B but specific rotation with an opposite sign warranted a revision of the absolute configuration of radicamine B.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Polyhydroxy Pyrrolidine Alkaloids; Radicamine B; Codonopsinine; Cyclic Nitrone; Grignard Addition |
| ID Code: | 11478 |
| Deposited On: | 16 Nov 2010 13:54 |
| Last Modified: | 02 Jun 2011 09:42 |
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