1D porous framework of copper(II) showing a novel coordination mode of Ni(CN)42−

Maji, Tapas Kumar ; Mukherjee, Partha Sarathi ; Chaudhuri, Nirmalendu Ray ; Mostafa, Golam ; Zangrando, Ennio (2001) 1D porous framework of copper(II) showing a novel coordination mode of Ni(CN)42− Chemical Communications (15). pp. 1368-1369. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2001...

Related URL: http://dx.doi.org/10.1039/B103823K

Abstract

A novel porous framework [{Cu2(medpt)2Ni(CN)4}(ClO4 )2· 2.5H2O]n 1, [medpt = bis(3-aminopropyl)methylamine] is prepared where all the CN groups of Ni(CN)42− are involved in bridging; this material retains single crystallinity upon removal of water guest molecules and the dehydrated species 2 selectively binds organic molecules.

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