Sain, Saugata ; Maji, Tapas Kumar ; Chaudhuri, Nirmalendu Ray ; Zangrando, Ennio (2002) Construction of a three-dimensional supramolecular network of manganese(II) with an encapsulated croconate dianion Transition Metal Chemistry, 27 (7). pp. 716-719. ISSN 0340-4285
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Official URL: https://link.springer.com/article/10.1023%2FA%3A10...
Related URL: http://dx.doi.org/10.1023/A:1020377401744
Abstract
A three-dimensional supramolecular polymer of manganese(II), [{Mn(4,4′-bipy)(H2O)4}(C5O5)(H2O)2] n has been prepared and characterized by X-ray single crystal analysis. The polymer results from the mutual relationship of each coordination unit, [Mn(4,4′-bipy)(H2O)4]2+ through H-bonding between crystalline water and the encapsulated croconate dianion. Solid state thermal investigation shows stepwise elimination of water molecules and the 4,4′-bipyridine ligand.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer-Verlag. |
| Keywords: | Polymer; Manganese; Catalysis; Water Molecule; Solid State |
| ID Code: | 114738 |
| Deposited On: | 29 May 2018 10:58 |
| Last Modified: | 29 May 2018 10:58 |
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