Kumar Maji, Tapas ; Mostafa, Golam ; Clemente-Juan, Juan M. ; Ribas, Joan ; Lloret, Francesc ; Okamoto, Ken-ichi ; Chaudhuri, Nirmalendu Ray (2003) Synthesis, crystal structure and magneto-structural correlation of an unusual thiocyanato-bridged nickel(II) compound, [Ni(μ-NCS)(dpt)(NCS)]2[Ni(μ-NCS)(dpt)(NCS)]4 [dpt = bis(3-aminopropyl)amine] European Journal of Inorganic Chemistry, 2003 (5). pp. 1005-1011. ISSN 1434-1948
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Official URL: https://onlinelibrary.wiley.com/doi/abs/10.1002/ej...
Related URL: http://dx.doi.org/10.1002/ejic.200390123
Abstract
Reaction of Ni(ClO4)2·6H2O with bis(3‐aminopropyl)amine (dpt) and ammonium thiocyanate produces the novel thiocyanato‐bridged nickel(II) compound [Ni(μ‐NCS)(dpt)(NCS)]2[Ni(μ‐NCS)(dpt)(NCS)]4, which has been structurally characterised. The structure determination reveals that there are two different molecules in the crystal lattice; one is dinuclear and other is tetranuclear. Low‐temperature magnetic measurements show that there are ferro‐ as well as antiferromagnetic interactions. The ferromagnetic interaction arises from the dinuclear part and the doubly bridged part of the tetranuclear unit; the antiferromagnetic interaction occurs between singly bridged nickel centres in the tetranuclear unit.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
| ID Code: | 114730 |
| Deposited On: | 29 May 2018 11:14 |
| Last Modified: | 29 May 2018 11:14 |
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