Ghoshal, Debajyoti ; Maji, Tapas Kumar ; Mostafa, Golam ; Lu, Tian-Huey ; Chaudhuri, Nirmalendu Ray (2003) A three-dimensional honeycomb-like network constructed with novel “sinusoidal” one-dimensional chains via hydrogen bonding and π−π interactions Crystal Growth & Design, 3 (1). pp. 9-11. ISSN 1528-7483
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Official URL: https://pubs.acs.org/doi/abs/10.1021/cg025574p
Related URL: http://dx.doi.org/10.1021/cg025574p
Abstract
A one pot reaction of MnCl2, acetylene dicarboxylate (C4O22-), and 1,2-bis(4-pyridyl)ethane (bpe) leads to a compound formulated as [{Mn(bpe)(H2O)4}(C4O4)·4.5H2O] and has been shown by single crystal structure analysis to be a three-dimensional network with hexagonal and rhombohedral channels encapsulating C4O42- and water molecules, constructed by the one-dimensional “sinusoidal” [Mn(bpe)(H2O)4]n2+ cationic chains through extensive hydrogen-bonding and π−π interactions.
Item Type: | Article |
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Source: | Copyright of this article belongs to American Chemical Society. |
ID Code: | 114729 |
Deposited On: | 29 May 2018 11:18 |
Last Modified: | 29 May 2018 11:18 |
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