Maji, Tapas Kumar ; Ghoshal, Debajyoti ; Zangrando, Ennio ; Ribas, Joan ; Chaudhuri, Nirmalendu Ray (2004) A novel 2D mixed valence copper(I/II) rectangular grid constructed with pyrazine and croconate CrystEngComm, 6 (101). pp. 623-626. ISSN 1466-8033
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2004...
Related URL: http://dx.doi.org/10.1039/B414642E
Abstract
A novel 2D rectangular grid coordination polymer with a mixed valence localized copper(I/II), [Cu2ICuII(pyz)2(C5O5)2 (H2O)2]n (pyz, pyrazine; C5O52−, croconate dianion) has been hydrothermally synthesized viain situ redox reaction of Cu(II), and characterized by X-ray diffraction analysis, magnetic and EPR study. The structure extends to a 3D supramolecular network through H-bonding.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 114719 |
| Deposited On: | 29 May 2018 08:47 |
| Last Modified: | 29 May 2018 08:47 |
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