Guest-induced asymmetry in a metal−organic porous solid with reversible single-crystal-to-single-crystal structural transformation

Maji, Tapas Kumar ; Mostafa, Golam ; Matsuda, Ryotaro ; Kitagawa, Susumu (2005) Guest-induced asymmetry in a metal−organic porous solid with reversible single-crystal-to-single-crystal structural transformation Journal of the American Chemical Society, 127 (49). pp. 17152-17153. ISSN 0002-7863

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Official URL: https://pubs.acs.org/doi/abs/10.1021/ja0561439

Related URL: http://dx.doi.org/10.1021/ja0561439

Abstract

A metal−organic honeycomb-like 2D pillared-bilayer open framework has been constructed which shows dynamic sponge-like single-crystal-to-single-crystal transformation upon dehydration and rehydration. The dehydrated acentric nonporous phase transformed to the porous centric phase with the selective adsorbate concomitant with the structural transformation correlated with the single-crystal structure determination.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:114707
Deposited On:30 May 2018 06:34
Last Modified:30 May 2018 06:34

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