Diversity in magnetic properties of 3D isomorphous networks of Co(II) and Mn(II) constructed by napthalene-1,4-dicarboxylate

Maji, Tapas Kumar ; Kaneko, Wakako ; Ohba, Masaaki ; Kitagawa, Susumu (2005) Diversity in magnetic properties of 3D isomorphous networks of Co(II) and Mn(II) constructed by napthalene-1,4-dicarboxylate Chemical Communications (36). pp. 4613-4615. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2005...

Related URL: http://dx.doi.org/10.1039/B507953E

Abstract

Two novel 3D isomorphous organic–inorganic hybrid frameworks, [M(1,4-napdc)]n ( M = Co(II), 1 and Mn(II), 2; 1,4-napdcH2 = napthalene-1,4-dicarboxylic acid) have been hydrothermally synthesized and structurally characterized, and the magnetic results exhibit metamagnetic behaviour (TC = 5.5 K) for 1, and a weak antiferromagnetic interaction for 2, which are structurally correlated.

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