Gurunatha, K. L. ; Maji, Tapas Kumar (2009) Guest-induced irreversible sliding in a flexible 2D rectangular grid with selective sorption characteristics Inorganic Chemistry, 48 (23). pp. 10886-10888. ISSN 0020-1669
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Official URL: https://pubs.acs.org/doi/abs/10.1021/ic901804a
Related URL: http://dx.doi.org/10.1021/ic901804a
Abstract
A 2D noninterpenetrated flexible metal-organic porous solid, {[Cu2(cis-chdc)2(bpee)]·H2O}n (1) based on a paddle-wheel building unit has been constructed using a mixed-ligand system. Guest-induced irreversible internetwork displacements of the 2D grids result in permanent porosity in the framework, as realized by the selective CO2 sorption over N2. The different affinity and selectivity of the solvent molecules was correlated with the internal polarity of the pore surfaces.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 114579 |
| Deposited On: | 30 May 2018 06:24 |
| Last Modified: | 30 May 2018 06:24 |
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