High heat of hydrogen adsorption and guest-responsive magnetic modulation in a 3D porous pillared-layer coordination framework

Hazra, Arpan ; Kanoo, Prakash ; Maji, Tapas Kumar (2011) High heat of hydrogen adsorption and guest-responsive magnetic modulation in a 3D porous pillared-layer coordination framework Chemical Communications, 47 (1). pp. 538-540. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2011...

Related URL: http://dx.doi.org/10.1039/C0CC02490B

Abstract

A bimetallic pillared-layer coordination framework {[Mn3(bipy)3(H2O)4][Cr(CN)6]2·2(bipy)·4(H2O)}n has been constructed using a cyanometallate anion ([Cr(CN)6]3−) and an organic linker (4,4′-bipyridyl) that provides high heat of hydrogen adsorption (∼11.5 kJ mol-1) and shows guest dependent magnetic modulation.

Item Type:Article
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ID Code:114555
Deposited On:29 May 2018 08:58
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