Mohapatra, Sudip ; Sato, Hiroshi ; Matsuda, Ryotaro ; Kitagawa, Susumu ; Maji, Tapas Kumar (2012) Highly rigid and stable porous Cu(I) metal–organic framework with reversible single-crystal-to-single-crystal structural transformation CrystEngComm, 14 (12). pp. 4153-4156. ISSN 1466-8033
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2012...
Related URL: http://dx.doi.org/10.1039/C2CE06701C
Abstract
A simple room temperature reaction of Cu(NO3)2, and 2,3-pyrazinedicarboxylic acid (H2pyzdc) in the presence of dihydroxyfumaric acid (DHFA) resulted in the formation of a highly stable 3D Cu(I) coordination polymer, {[Cu2(pyzdc)]·0.83H2O}n where DHFA acts as a reducing agent. It possesses a 1D water filled channel along the crystallographic c direction and the framework shows reversible single-crystal-to-single-crystal structural transformation upon dehydration and rehydration.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 114510 |
| Deposited On: | 29 May 2018 08:21 |
| Last Modified: | 29 May 2018 08:21 |
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