Synthesis of (3R, 4R)-1, 2-divinylglycol and its unsymmetrical derivatives: an application to the synthesis of R-(+)-α-lipoic acid

Yadav, J. S. ; Mysorekar, Sudha V. ; Pawar, Sushma M. ; Gurjar, M. K. (1990) Synthesis of (3R, 4R)-1, 2-divinylglycol and its unsymmetrical derivatives: an application to the synthesis of R-(+)-α-lipoic acid Journal of Carbohydrate Chemistry, 9 (2-3). pp. 307-316. ISSN 0732-8303

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Official URL: http://www.informaworld.com/index/790960942.pdf

Related URL: http://dx.doi.org/10.1080/07328309008543834

Abstract

The synthesis of (3R, 4R)-divinylglycol (1) and some of its unsymmetrical derivatives has been described starting from D-mannitol. I has been converted into R-(+)-α-lipoic acid.

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