Ratiometric sensing of Hg2+ based on the calix[4]arene of partial coneconformation possessing a dansyl moiety

Dhir, Abhimanew ; Bhalla, Vandana ; Kumar, Manoj (2008) Ratiometric sensing of Hg2+ based on the calix[4]arene of partial coneconformation possessing a dansyl moiety Organic Letters, 10 (21). pp. 4891-4894. ISSN 1523-7060

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Official URL: https://pubs.acs.org/doi/abs/10.1021/ol801984y

Related URL: http://dx.doi.org/10.1021/ol801984y

Abstract

A new fluorescent chemosensor based on the calix[4]arene of partial cone conformation possessing a dansyl moiety has been synthesized. The chemosensor demonstrates selective optical recognition of Hg2+ and Cu2+ in two contrasting modes. The receptor exhibited ratiometric sensing of Hg2+ and “ON−OFF” type of fluorescence behavior in the presence of Cu2+. The compound behaves as a fluorescent molecular switch upon chemical inputs of Hg2+ and Cu2+ ions.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:114455
Deposited On:18 May 2018 10:42
Last Modified:18 May 2018 10:42

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