Empowering transition-metal-free cascade protocol for the green synthesis of biaryls and alkynes

Walia, Preet Kamal ; Kumar, Manoj ; Bhalla, Vandana (2018) Empowering transition-metal-free cascade protocol for the green synthesis of biaryls and alkynes ACS Omega, 3 (2). pp. 1983-1990. ISSN 2470-1343

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Official URL: https://pubs.acs.org/doi/full/10.1021/acsomega.7b0...

Related URL: http://dx.doi.org/10.1021/acsomega.7b02014

Abstract

The work being presented in this paper demonstrates the simple and efficient “transition-metal-free” and “light-mediated” synthetic protocol for the synthesis of aryl iodides/biaryls/alkynes from aryl bromides. Under ultraviolet irradiation and in basic aqueous media, aryl bromides undergo transformation into aryl iodides which efficiently couple via a cascade reaction with a wide range of terminal alkynes/unactivated arenes to generate target molecules under green conditions.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:114420
Deposited On:18 May 2018 08:50
Last Modified:18 May 2018 08:50

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