Kumar, Rajesh ; Bhalla, Vandana ; Kumar, Manoj (2008) Cu2+ and CN−-selective fluorogenic sensors based on pyrene-appended thiacalix[4]arenes Tetrahedron, 64 (35). pp. 8095-8101. ISSN 0040-4020
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Official URL: https://www.sciencedirect.com/science/article/pii/...
Related URL: http://dx.doi.org/10.1016/j.tet.2008.06.064
Abstract
Two new fluorescent sensors 1 and 2 based on thiacalix[4]arenes bearing pyrene moieties have been synthesized in cone conformation. The binding abilities of these sensors towards different cations such as lithium, sodium, potassium, nickel, cadmium, copper, zinc, lead, silver, mercury and anions like fluoride, chloride, bromide, iodide, cyanide, acetate, hydrogen sulfate and nitrate have been examined by UV–vis and fluorescence spectroscopies. These receptors show pronounced selectivity for copper and cyanide ions. In CH2Cl2/CH3CN (1:1), the presence of Cu(II) ion induces the formation of 1:1 (H/G) complex with receptor 1 and 1:2 (H/G) complex with receptor 2. The cyanide ions form a 1:1 (H/G) complex with both receptors.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Fluorogenic Sensors; Thiacalix[4]arene; Copper; Cyanide |
| ID Code: | 114117 |
| Deposited On: | 18 May 2018 08:54 |
| Last Modified: | 18 May 2018 08:54 |
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