Kumar, Manoj ; Kumar, Rajesh ; Bhalla, Vandana (2009) F−-Induced ‘turn-on’ fluorescent chemosensor based on 1,3-alt thiacalix[4]arene Tetrahedron, 65 (22). pp. 4340-4344. ISSN 0040-4020
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Official URL: https://www.sciencedirect.com/science/article/pii/...
Related URL: http://dx.doi.org/10.1016/j.tet.2009.03.074
Abstract
A new thiacalix[4]arene based fluorescent sensor 1 bearing two naphthyl groups has been synthesized in 1,3-alternate conformation. In the absence of fluoride ion, the receptor 1 is in ‘off-state’ showing no fluorescence emission. The presence of fluoride ion triggered the fluorescence emission to ‘on-state’. The receptor shows pronounced selectivity for fluoride ions. In THF, the presence of F− ions induces the formation of a 1:1 (G:H) complex.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
Keywords: | Fluorogenic Chemosensor; Thiacalix[4]arene; Fluoride |
ID Code: | 114070 |
Deposited On: | 18 May 2018 08:54 |
Last Modified: | 18 May 2018 08:54 |
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