Bhalla, Vandana ; Gupta, Ankush ; Singh, Hardev ; Kumar, Manoj (2011) Fluoride-induced cyclization of pentacenequinone to higher quinones Journal of Organic Chemistry, 76 (6). pp. 1578-1583. ISSN 0022-3263
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Official URL: https://pubs.acs.org/doi/abs/10.1021/jo101996k
Related URL: http://dx.doi.org/10.1021/jo101996k
Abstract
Novel pentacenequinone derivatives 3, 7, and 10 have been synthesized via Suzuki−Miyaura coupling. Derivatives 3 and 7 having OTBS groups undergo irreversible fluoride-induced cyclization to substituted higher quinones in the presence of TBAF in dry THF using one-pot, two-step strategies in moderate yields. These functionalized higher quinone derivatives are freely soluble in THF and DMSO and can be used as precursors for the synthesis of higher acene derivatives.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 114028 |
| Deposited On: | 18 May 2018 08:28 |
| Last Modified: | 18 May 2018 08:28 |
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