Gopinath, Rangam ; Barkakaty, Balaka ; Talukdar, Bandana ; Patel, Bhisma K. (2003) Peroxovanadium-catalyzed oxidative esterification of aldehydes The Journal of Organic Chemistry, 68 (7). pp. 2944-2947. ISSN 0022-3263
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Official URL: https://pubs.acs.org/doi/abs/10.1021/jo0266902
Related URL: http://dx.doi.org/10.1021/jo0266902
Abstract
The peroxovanadium species generated from V2O5 and hydrogen peroxide, which is liberated from peroxy salts such as sodium perborate (SPB) or sodium percarbonate (SPC), transform aldehydes directly into esters in an alcoholic medium. Monoesters of diols have been achieved directly in one pot from aldehydes. High catalytic turnover number combined with inexpensive, easily available reagents and innocuous side products from the reaction make it a suitable alternative for the synthesis of esters from aldehydes.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 113970 |
| Deposited On: | 02 May 2018 04:51 |
| Last Modified: | 02 May 2018 04:51 |
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