Majji, Ganesh ; Guin, Srimanta ; Gogoi, Anupal ; Rout, Saroj Kumar ; Patel, Bhisma K. (2013) Easy access to benzylic esters directly from alkyl benzenes under metal-free conditions Chemical Communications, 49 (29). pp. 3031-3033. ISSN 1359-7345
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2013...
Related URL: http://dx.doi.org/10.1039/C3CC40832A
Abstract
An efficient metal free protocol has been developed for the synthesis of benzylic esters via a Cross Dehydrogenative Coupling (CDC) involving alkylbenzene(s) as a self- or as a cross-coupling partner(s) via the intermediacy of Ar–COOH and the benzylic carbocation obtained from the other half of the alkylbenzene; both symmetrical as well as unsymmetrical esters can be prepared using Bu4NI and TBHP.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 113882 |
| Deposited On: | 30 Apr 2018 12:11 |
| Last Modified: | 30 Apr 2018 12:11 |
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