Easy access to benzylic esters directly from alkyl benzenes under metal-free conditions

Majji, Ganesh ; Guin, Srimanta ; Gogoi, Anupal ; Rout, Saroj Kumar ; Patel, Bhisma K. (2013) Easy access to benzylic esters directly from alkyl benzenes under metal-free conditions Chemical Communications, 49 (29). pp. 3031-3033. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2013...

Related URL: http://dx.doi.org/10.1039/C3CC40832A

Abstract

An efficient metal free protocol has been developed for the synthesis of benzylic esters via a Cross Dehydrogenative Coupling (CDC) involving alkylbenzene(s) as a self- or as a cross-coupling partner(s) via the intermediacy of Ar–COOH and the benzylic carbocation obtained from the other half of the alkylbenzene; both symmetrical as well as unsymmetrical esters can be prepared using Bu4NI and TBHP.

Item Type:Article
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ID Code:113882
Deposited On:30 Apr 2018 12:11
Last Modified:30 Apr 2018 12:11

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